BSC LLB

COMPULSORY COURSE *** I-SEMESTER Course Code Course Title LGE-101 General English LBS-102 Chemistry-I LBS-103 Life Science-I LAW-111 Right to Information LAW-112 Contracts- I (General Principles) B.Sc., LL.B. (Five Years Course) I-SEMESTER (LGE-101) General English (The Theory Paper shall be of 70 marks and of 3 hours duration. The question asked may be objective and subjective both or subjective only. 30 Marks have been assigned for sessionals) SYLLABUS: I. 1. Basis Sentence Patterns 2. Tenses 3. Transformation and Formations of Interrogative and Negative Sentences 4. Tag – Questions 5. Model Auxiliaries 6. Word-formation II. 1. Passive Constructions 2. Narration : Direct and Indirect 3. Translation from Hindi to English and English to Hindi 4. Conditional Sentences 5. Word Formation (Conditional) III. 1. Translation (Continued) 2. Determiners and Articles 3. Idioms and Phrases 4. Spelling Exercises Suggested Readings: 1. A Practical English Grammar. Thomson and Martinet 2. Webster”s Spelling Dictionary 3. Living English by Dr. R.P.Bhatnagar & Rajul Bhargava 4. Current English Usage. R.H.Flavell and L.H.Flavell 5. Legal English. R.L.Jain 6. General English. Mr.Rastogi 7. General English. Mr.Tanwar 8. J.S. Allen : ‘English Grammar *** B.Sc., LL.B. (Five Years Course) I-SEMESTER (LBS-102) Chemistry-I (Organic Chemistry) (The Theory Paper shall be of 70 marks and of 3 hours duration. The question asked may be objective and subjective both or subjective only. 30 Marks have been assigned for sessionals) 1. Stereochemistry : Elements of symmetry, Molecular Chirality, Enantiomers, Stereogenic center, Optical activity, Properties of enantiomers, Chiral and achiral molecules with two stereogenic centers, Disastereomers, threo and erythro diastereomers, Meso compounds, Racemisation and resolution, relative and absolute configuration, Sequence rules, Systems of nomenclature (D,L,R and S), Optical isomerism due to restricted rotation - diphenyl systems. II. Reactive Intermediaries : carbenes, nitrenes, yields, Structure-activity relationship, Slected name freactions – Acyloin Condensation, Perkin Reaction, Wittig reaction, Mat Eistert Reaction, Birch Reduction; Geometric isomerism – determination of configuration of geometric isomers, E and Z systems of nomenclature, Geometric isomerism in oximes and alicyclic compound – Confirmations of mono and disubstituted cyclohexanes III. Pericyclic Reactions (6 hours): Theory and applications, Heterocyclic Compounds – Chemistry of furan, pyrrole, pyridine, indole, quioline, isoquinoline, imidazole, pyrimidine and purine – chemistry of mono and disaccharides IV. Amines (6 hours): Nomenclature and classification; Basic nature; Preparation of alkyl and aryl amines – Reduction of nitro compounds, Nitriles, Reductive amination of carbonyl compounds, Gabriel-phthalimide synthesis and Hofmann bromamide reaction, Reactions of amines as nucleophiles, diazotisation; distinguishing reaction between 1, 2 and 3 degree amines, Synthetic application of diazonium salt V. Principles of Organic Synthesis ( 8 hours): Methods of Carbon – Carbon bond formation, use of organometallic reagents, Ring forming Reactions, Baldwin‖ Rule, Umpolung and functional group manipulations, protecting groups, asymmetric synthesis- chemical and Enzymatic Approaches Novel Oxidizing and Reducing Agents, Phase Transfer, Transition Metal and Enzyme catalysis, Chiral Reagents and Catalysis VI. Natural Products (12): Carbohydrates – Introduction, Classification, Ring structure of glucose in detail, Interconversion of glucose and fructose – Mechanism of mutarotation; structure of galatose, Mannose and fructose; Glycosidic bond – Disaccharides, structure of maltose, Lactose, sucrose Z terpenoids: Occurrence, Classification and isoprene rule; Elucidation of structure and synthesis of citral and a-terphenol; Structure of menthol, Camphor, Limonene and Bita-carotene and their uses Alkaloids: Classification, General characteristics; Structure elucidation and synthesis of nicotine; Uses of Quinine, Morphine, Strychnine, Cocaine, Atropine, Reserpine and nicotine Experiments : Qualitative tests for Identification of Organic Compounds, Separation and Purification Techniques in Organic Chemistry, Recrystallization, Distillation, Extraction Perkin Reaction of Salicyldehyde, Cannizaro Reaction of Furfural, Synthesis of O – Iodobenzoic acid, Benzilic acid and m – Nitrobenzoic acid Kinetics of salt effect and ionic strength; determination of activation of energy in the bromide-bromate clock reaction and acid hydrolysis of ethyl acctate Suggested Readings: